Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution

Clare Bakewell; Andrew J.P. White; Mark R. Crimmin

doi:10.1021/jacs.6b08104

Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution

Clare Bakewell, Andrew J.P. White, Mark R. Crimmin^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.

Original language	English
Pages (from-to)	12763-12766
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	39
DOIs	https://doi.org/10.1021/jacs.6b08104
Publication status	Published - 5 Oct 2016

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title = "Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution",

abstract = "Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.",

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AU - Crimmin, Mark R.

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N2 - Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.

AB - Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.

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U2 - 10.1021/jacs.6b08104

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IS - 39

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Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution

Abstract

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