Observation of dihydrated glycine

Jose L. Alonso; Isabel Pena; Maria Eugenia Sanz; Vanesa Vaquero; Santiago Mata; Carlos Cabezas; Juan C. Lopez

doi:10.1039/c3cc40344k

Observation of dihydrated glycine

Jose L. Alonso^*, Isabel Pena, Maria Eugenia Sanz, Vanesa Vaquero, Santiago Mata, Carlos Cabezas, Juan C. Lopez

^*Corresponding author for this work

Chemistry

Universidad de Valladolid

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The complex of glycine with two water molecules glycine-(H2O)(2) has been generated by laser ablation in a supersonic expansion and characterised using rotational spectroscopy. The water molecules bind to the carboxylic group of glycine and to each other through three intermolecular hydrogen bonds, closing an eight-membered ring. In the complex, glycine adopts the conformation found to be the most stable for bare glycine.

Original language	English
Article number	N/A
Pages (from-to)	3443-3445
Number of pages	3
Journal	CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY
Volume	49
Issue number	33
DOIs	https://doi.org/10.1039/c3cc40344k
Publication status	Published - 1 Mar 2013

Keywords

MILLIMETER WAVE SPECTRUM
SEEDED SUPERSONIC JETS
CONFORMERS
WATER
MICROSOLVATION
RELAXATION
ACID

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title = "Observation of dihydrated glycine",

abstract = "The complex of glycine with two water molecules glycine-(H2O)(2) has been generated by laser ablation in a supersonic expansion and characterised using rotational spectroscopy. The water molecules bind to the carboxylic group of glycine and to each other through three intermolecular hydrogen bonds, closing an eight-membered ring. In the complex, glycine adopts the conformation found to be the most stable for bare glycine.",

keywords = "MILLIMETER WAVE SPECTRUM, SEEDED SUPERSONIC JETS, CONFORMERS, WATER, MICROSOLVATION, RELAXATION, ACID",

author = "Alonso, {Jose L.} and Isabel Pena and Sanz, {Maria Eugenia} and Vanesa Vaquero and Santiago Mata and Carlos Cabezas and Lopez, {Juan C.}",

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doi = "10.1039/c3cc40344k",

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TY - JOUR

T1 - Observation of dihydrated glycine

AU - Alonso, Jose L.

AU - Pena, Isabel

AU - Sanz, Maria Eugenia

AU - Vaquero, Vanesa

AU - Mata, Santiago

AU - Cabezas, Carlos

AU - Lopez, Juan C.

PY - 2013/3/1

Y1 - 2013/3/1

N2 - The complex of glycine with two water molecules glycine-(H2O)(2) has been generated by laser ablation in a supersonic expansion and characterised using rotational spectroscopy. The water molecules bind to the carboxylic group of glycine and to each other through three intermolecular hydrogen bonds, closing an eight-membered ring. In the complex, glycine adopts the conformation found to be the most stable for bare glycine.

AB - The complex of glycine with two water molecules glycine-(H2O)(2) has been generated by laser ablation in a supersonic expansion and characterised using rotational spectroscopy. The water molecules bind to the carboxylic group of glycine and to each other through three intermolecular hydrogen bonds, closing an eight-membered ring. In the complex, glycine adopts the conformation found to be the most stable for bare glycine.

KW - MILLIMETER WAVE SPECTRUM

KW - SEEDED SUPERSONIC JETS

KW - CONFORMERS

KW - WATER

KW - MICROSOLVATION

KW - RELAXATION

KW - ACID

U2 - 10.1039/c3cc40344k

DO - 10.1039/c3cc40344k

M3 - Article

SN - 1359-7345

VL - 49

SP - 3443

EP - 3445

JO - CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY

JF - CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY

IS - 33

M1 - N/A

ER -

Observation of dihydrated glycine

Abstract

Keywords

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