The effect of unsaturated fatty acids in benzyl alcohol on the percutaneous permeation of three model penetrants

G R Nanayakkara, A Bartlett, B Forbes, C Marriott, P J Whitfield, M B Brown

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46 Citations (Scopus)

Abstract

The model penetrants butyl paraben (BP), methyl paraben (MP) and caffeine (CF), because of their different octanol/water partition coefficients and postulated routes of permeation through human skin, were selected to assess the enhancing activity of pre-treatment solutions consisting of monounsaturated (oleic (OA) and palmitoleic (PA)) and poly-unsaturated (linoleic (LA)) fatty acids in benzyl alcohol (BA) using Franz diffusion cells and HPLC detection. Prior to assessing the effect of penetrant lipophilicity, NIP was chosen to investigate the concentration-dependent effect of fatty acids in pre-treatment solutions. At 5% (w/w) fatty acids in BA, only pre-treatment solutions containing palmitoleic acid (PA) increased the permeation of MP when compared to pre-treatment with BA alone, whereas at higher concentrations (10 and 20%, w/w), all pre-treatment solutions except 10% OA produced a significant increase in MP flux (P <0.05). The general order of fatty acid effectiveness at any concentration was PA > LA > OA. At 20% (w/w) fatty acids in BA, all pre-treatment solutions significantly enhanced the permeation of all three penetrants (P
Original languageEnglish
Pages (from-to)129 - 139
Number of pages11
JournalINTERNATIONAL JOURNAL OF PHARMACEUTICS
Volume301
Issue number1-2
DOIs
Publication statusPublished - 14 Sept 2005

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